TMISAT 2017 or Tolani Maritime Institute of Science Aptitude Test is one of the largest maritime educational exams offering Marine Engineering and Nautical Technology degree programs.TMI graduates are awarded B.Tech. Marine Engineering and B.Tech. Nautical Technology degrees by the well-established Birla Institute of Technology and Science (BITS) Pilani, a deemed university widely recognized as one of India’s preeminent centers for technology education.TMISAT is an online entrance examination conducted by Tolani Maritime. Tolani Maritime Institute is situated in Pune and conducts the entrance examination in collaboration with Birla Institute of Technology and Science. These engineering programmes fall under the category of the off campus courses provided by the Birla Institute of Technology and Science. The selection process has 3 steps: Online test, Personal Interview and Medical Examination.
|Date of Examination||07 May 2017|
|Time of Examination||9:00 AM|
Eligibility Criteria for TMISAT 2017:
Candidates must fulfill basic TMISAT Eligibility Criteria to be able to apply for the desired programme. All candidates must ensure that they go through the eligibility criteria for TMISAT before applying for TMISAT. If a candidate does not satisfy the eligibility criteria, they will not be allowed to write the exam as it is essential for all candidates to satisfy the eligibility criteria for TMISAT.
The TMISAT 2017 eligibility criteria is as follows:
|Starting date of registration||01 January 2017|
|Last date of registration||31 March 2017|
Syllabus for TMISAT 2017:
TMISAT 2017 syllabus is based on 11th and 12th CBSE standard Physics, Chemistry and Mathematics syllabus plus English grammar, vocabulary and Logical & Analytical reasoning.
Some Basic Concepts of Chemistry
General Introduction: Importance and scope of chemistry.
Nature of matter, laws of chemical combination, Dalton's atomic theory: concept of elements, atoms and molecules.
Atomic and molecular masses, mole concept and molar mass, percentage composition, empirical and molecular formula, chemical reactions, stoichiometry and calculations based on stoichiometry.
Structure of Atom
Discovery of Electron, Proton and Neutron, atomic number, isotopes and isobars. Thomson's model and its limitations. Rutherford's model and its limitations, Bohr's model and its limitations, concept of shells and subshells, dual nature of matter and light, de Broglie's relationship, Heisenberg uncertainty principle, concept of orbitals, quantum numbers, shapes of s, p and d orbitals, rules for filling electrons in orbitals - Aufbau principle, Pauli's exclusion principle and Hund's rule, electronic configuration of atoms, stability of half filled and completely filled orbitals.
Classification of Elements and Periodicity in Properties
Significance of classification, brief history of the development of periodic table, modern periodic law and the present form of periodic table, periodic trends in properties of elements -atomic radii, ionic radii, inert gas radii Ionization enthalpy, electron gain enthalpy, electronegativity, valency. Nomenclature of elements with atomic number greater than 100.
Chemical Bonding and Molecular Structure
Valence electrons, ionic bond, covalent bond; bond parameters, Lewis structure, polar character of covalent bond, covalent character of ionic bond, valence bond theory, resonance, geometry of covalent molecules, VSEPR theory, concept of hybridization, involving s,p and d orbitals and shapes of some simple molecules, molecular orbital theory of homonuclear diatomic molecules (qualitative idea only), hydrogen bond.
States of Matter: Gases and Liquids
Three states of matter, intermolecular interactions, types of bonding, melting and boiling points, role of gas laws in elucidating the concept of the molecule, Boyle's law, Charles law, Gay Lussac's law, Avogadro's law, ideal behaviour, empirical derivation of gas equation, Avogadro's number, ideal gas equation. Deviation from ideal behaviour, liquefaction of gases, critical temperature, kinetic energy and molecular speeds (elementary idea)Liquid State- vapour pressure, viscosity and surface tension (qualitative idea only, no mathematical derivations)
Concepts of System and types of systems, surroundings, work, heat, energy, extensive and intensive properties, state functions.
First law of thermodynamics -internal energy and enthalpy, heat capacity and specific heat, measurement of ?U and ?H, Hess's law of constant heat summation, enthalpy of bond dissociation, combustion, formation, atomization, sublimation, phase transition, ionization, solution and dilution. Second law of Thermodynamics (brief introduction)
Introduction of entropy as a state function, Gibb's energy change for spontaneous and non-spontaneous processes, criteria for equilibrium.
Third law of thermodynamics (brief introduction).
Equilibrium in physical and chemical processes, dynamic nature of equilibrium, law of mass action, equilibrium constant, factors affecting equilibrium - Le Chatelier's principle, ionic equilibrium-ionization of acids and bases, strong and weak electrolytes, degree of ionization, ionization of poly basic acids, acid strength, concept of pH, Henderson Equation, hydrolysis of salts (elementary idea), buffer solution, solubility product, common ion effect (with illustrative examples).
Concept of oxidation and reduction, redox reactions, oxidation number, balancing redox reactions, in terms of loss and gain of electrons and change in oxidation number, applications of redox reactions.
Position of hydrogen in periodic table, occurrence, isotopes, preparation, properties and uses of hydrogen, hydrides-ionic covalent and interstitial; physical and chemical properties of water, heavy water, hydrogen peroxide -preparation, reactions and structure and use; hydrogen as a fuel.
s -Block Elements (Alkali and Alkaline Earth Metals)
Group 1 and Group 2 Elements
General introduction, electronic configuration, occurrence, anomalous properties of the first element of each group, diagonal relationship, trends in the variation of properties (such as ionization enthalpy, atomic and ionic radii), trends in chemical reactivity with oxygen, water, hydrogen and halogens, uses.
Preparation and Properties of Some Important Compounds:
Sodium Carbonate, Sodium Chloride, Sodium Hydroxide and Sodium Hydrogencarbonate, Biological importance of Sodium and Potassium. Calcium Oxide and Calcium Carbonate and their industrial uses, biological importance of Magnesium and Calcium.
Some p -Block Elements
General Introduction to p - Block Elements
Group 13 Elements: General introduction, electronic configuration, occurrence, variation of properties, oxidation states, trends in chemical reactivity, anomalous properties of first element of the group, Boron - physical and chemical properties, some important compounds, Borax, Boric acid, Boron Hydrides, Aluminium: Reactions with acids and alkalies, uses.
Group 14 Elements: General introduction, electronic configuration, occurrence, variation of properties, oxidation states, trends in chemical reactivity, anomalous behaviour of first elements. Carbon-catenation, allotropic forms, physical and chemical properties; uses of some important compounds: oxides. Important compounds of Silicon and a few uses: Silicon Tetrachloride, Silicones, Silicates and Zeolites, their uses.
Organic Chemistry - Some Basic Principles and Technique
General introduction, methods of purification, qualitative and quantitative analysis, classification and IUPAC nomenclature of organic compounds. Electronic displacements in a covalent bond: inductive effect, electromeric effect, resonance and hyper conjugation. Homolytic and heterolytic fission of a covalent bond: free radicals, carbocations, carbanions, electrophiles and nucleophiles, types of organic reactions.
Classification of Hydrocarbons
Alkanes - Nomenclature, isomerism, conformation (ethane only), physical properties, chemical reactions including free radical mechanism of halogenation, combustion and pyrolysis.
Alkenes - Nomenclature, structure of double bond (ethene), geometrical isomerism, physical properties, methods of preparation, chemical reactions: addition of hydrogen, halogen, water, hydrogen halides (Markownikov's addition and peroxide effect), ozonolysis, oxidation, mechanism of electrophilic addition.
Alkynes - Nomenclature, structure of triple bond (ethyne), physical properties, methods of preparation, chemical reactions: acidic character of alkynes, addition reaction of - hydrogen, halogens, hydrogen halides and water.
Aromatic Hydrocarbons: Introduction, IUPAC nomenclature, benzene: resonance, aromaticity, chemical properties: mechanism of electrophilic substitution. nitration, sulphonation, halogenation, Friedel Craft's alkylation and acylation, directive influence of functional group in monosubstituted benzene. Carcinogenicity and toxicity.
Environmental pollution - air, water and soil pollution, chemical reactions in atmosphere, smog, major atmospheric pollutants, acid rain, ozone and its reactions, effects of depletion of ozone layer, greenhouse effect and global warming- pollution due to industrial wastes, green chemistry as an alternative tool for reducing pollution, strategies for control of environmental pollution.
Classification of solids based on different binding forces: molecular, ionic, covalent and metallic solids, amorphous and crystalline solids (elementary idea). Unit cell in two dimensional and three dimensional lattices, calculation of density of unit cell, packing in solids, packing efficiency, voids, number of atoms per unit cell in a cubic unit cell, point defects, electrical and magnetic properties.
Band theory of metals, conductors, semiconductors and insulators and n & p type semiconductors.
Types of solutions, expression of concentration of solutions of solids in liquids, solubility of gases in liquids, solid solutions, colligative properties - relative lowering of vapour pressure, Raoult's law, elevation of boiling point, depression of freezing point, osmotic pressure, determination of molecular masses using colligative properties, abnormal molecular mass, van't Hoff factor.
Redox reactions, conductance in electrolytic solutions, specific and molar conductivity, variations of conductivity with concentration, Kohlrausch's Law, electrolysis and law of electrolysis (elementary idea), dry cell -electrolytic cells and Galvanic cells, lead accumulator, EMF of a cell, standard electrode potential, Nernst equation and its application to chemical cells, Relation between Gibbs energy change and emf of a cell, fuel cells, corrosion.
Rate of a reaction (Average and instantaneous), factors affecting rate of reaction: concentration, temperature, catalyst; order and molecularity of a reaction, rate law and specific rate constant, integrated rate equations and half life (only for zero and first order reactions), concept of collision theory (elementary idea, no mathematical treatment). Activation energy, Arrhenious equation.
Adsorption - physisorption and chemisorption, factors affecting adsorption of gases on solids, catalysis, homogenous and heterogenous activity and selectivity; enzyme catalysis colloidal state distinction between true solutions, colloids and suspension; lyophilic , lyophobic multimolecular and macromolecular colloids; properties of colloids; Tyndall effect, Brownian movement, electrophoresis, coagulation, emulsion - types of emulsions.
General Principles and Processes of Isolation of Elements
Principles and methods of extraction - concentration, oxidation, reduction - electrolytic method and refining; occurrence and principles of extraction of aluminium, copper, zinc and iron.
p - Block Elements
Group 15 Elements: General introduction, electronic configuration, occurrence, oxidation states, trends in physical and chemical properties; nitrogen preparation properties & uses ; compounds of nitrogen, preparation and properties of ammonia and nitric acid, oxides of nitrogen (Structure only) ; Phosphorus - allotropic forms, compounds of phosphorus: preparation and properties of phosphine, halides PCl3 , PCl5 and oxoacids (elementary idea only).
Group 16 Elements: General introduction, electronic configuration, oxidation states, occurrence, trends in physical and chemical properties,dioxygen: Preparation, Properties and uses, classification of oxides, Ozone, Sulphure -allotropic forms; compounds of sulphure: Preparation properties and uses of sulphur-dioxide, sulphuric acid: industrial process of manufacture, properties and uses; oxoacids of sulphur (Structures only).
Group 17 Elements: General introduction, electronic configuration, oxidation states, occurrence, trends in physical and chemical properties; compounds of halogens, Preparation properties and uses of chlorine and hydrochloric acid, interhalogen compounds, oxoacids of halogens (structures only).
Group 18 Elements: General introduction, electronic configuration, occurrence, trends in physical and chemical properties, uses.
d and f Block Elements
General introduction, electronic configuration, occurrence and characteristics of transition metals, general trends in properties of the first row transition metals - metallic character, ionization enthalpy, oxidation states, ionic radii, colour, catalytic property, magnetic properties, interstitial compounds, alloy formation, preparation and properties of K2Cr2O7 and KMnO4.
Lanthanoids - Electronic configuration, oxidation states, chemical reactvity and lanthanoid contraction and its consequences.
Actinoids - Electronic configuration, oxidation states and comparison with lanthanoids.
Coordination compounds - Introduction, ligands, coordination number, colour, magnetic properties and shapes, IUPAC nomenclature of mononuclear coordination compounds. Bonding, Werner's theory, VBT, and CFT; structure and stereo isomerism, importance of coordination compounds (in qualitative inclusion, extraction of metals and biological system).
Haloalkanes and Haloarenes
Haloalkanes: Nomenclature, nature of C-X bond, physical and chemical properties, mechanism of substitution reactions, optical rotation.
Haloarenes: Nature of C -X bond, substitution reactions (Directive influence of halogen in monosubstituted compounds only.
Uses and environmental effects of - dichloromethane, trichloromethane, tetrachloromethane, iodoform freons, DDT.
Alcohols, Phenols and Ethers
Alcohols: Nomenclature, methods of preparation, physical and chemical properties( of primary alcohols only), identification of primary, secondary and tertiary alcohols, mechanism of dehydration, uses with special reference to methanol and ethanol.
Phenols: Nomenclature, methods of preparation, physical and chemical properties, acidic nature of phenol, electrophillic substitution reactions, uses of phenols.
Ethers: Nomenclature, methods of preparation, physical and chemical properties, uses.
Aldehydes, Ketones and Carboxylic Acids
Aldehydes and Ketones: Nomenclature, nature of carbonyl group, methods of preparation, physical and chemical properties, mechanism of nucleophillic addition, reactivity of alpha hydrogen in aldehydes: uses.
Carboxylic Acids: Nomenclature, acidic nature, methods of preparation, physical and chemical properties; uses.
Organic compounds containing Nitrogen
Amines: Nomenclature, classification, structure, methods of preparation, physical and chemical properties, uses, identification of primary, secondary and tertiary amines.
Cyanides and Isocyanides - will be mentioned at relevant places in context.
Diazonium salts: Preparation, chemical reactions and importance in synthetic organic chemistry.
Sets and Functions
2. Relations & Functions
3. Trigonometric Functions
syllabus 11 maths1
1. Principle of Mathematical Induction
2. Complex Numbers and Quadratic Equations
3. Linear Inequalities
4. Permutations and Combinations
5. Binomial Theorem
6. Sequence and Series
syllabus 11 maths2
1. Straight Lines
2. Conic Sections
3. Introduction to Three–dimensional Geometry
1. Limits and Derivatives
1. Mathematical Reasoning
1. Relations and Functions
2. Inverse Trigonometric Functions
1. Continuity and Differentiability
2. Applications of Derivatives
4. Applications of the Integrals
5. Differential Equations
dy/dx + py = q, where p and q are functions of x or constants.
dx/dy + px = q, where p and q are functions of y or constants.
Vectors and Three-Dimensional Geometry
2. Three - dimensional Geometry
1. Linear Programming
|Mode of application||
Application process for TMISAT 2017:
The process of TMISAT application is online as well as offline and ends on March 2017.
The documents required to complete the TMISAT application process are listed below:
The registration fee for the TMISAT exam is Rs.1000/-
|Tolani Maritime Institute of Science Aptitude Test [TMISAT] 2017 scores||Tolani Maritime Institute of Science Aptitude Test [TMISAT] 2017|
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